The Biden administration says it could soon launch a formal evaluation of risks posed by vinyl chloride, the cancer-causing chemical that burned in a towering plume of toxic smoke following the fiery train derailment in East Palestine, Ohio

Football, bloody hell, as Sir Alex Ferguson famously exclaimed after an action-packed finale against Bayern Munich. Manchester United had the final say again, Casemiro’s second goal meaning they got three in the Allianz Arena. Yet on a night of some surreal developments, there was a certain predictability, too. Of course Harry Kane scored. Bayern Munich bought him to be reassuringly reliable. Of course United lost, too, because that felt like a guarantee for a team with an acute self-destructive streak and even as they can savour the fact that the striker they did get instead of Kane, Rasmus Hojlund, opened his account. But as United’s third successive defeat was a tale of three summer signings, the notion it would come down to Kane against Hojlund, the master and the apprentice of goalscoring, overlooked United’s increasingly acute goalkeeping issue. While United named three goalkeepers on their bench, the problem was the one they had on the Allianz Arena pitch. Andre Onana was a Champions League finalist last season and arguably the outstanding shot-stopper in the competition. If Erik ten Hag thought he was buying a guarantee of their own, a Kane of goalkeeping, the Cameroonian marred his United bow in the competition with a horrible error, gifting Leroy Sane the opener and Bayern a path to a victory that, despite United’s three goals, rarely felt in doubt thereafter. While Jamal Musiala was outstanding, Thomas Tuchel’s team did not justify their billing among the favourites to win the competition. Nor did they need to. After 27 minutes of mediocrity from Bayern, Onana blundered, Sane scored and his torrid start to the season moved into the realms of the terrible. Short of players and confidence, United desperately require solidity, something to give them a platform they can build upon. Instead, for the first time since 2001, they have conceded at least two goals in five successive matches. Onana has been culpable for several of the 14, to varying degrees, but none as much as Sane’s limp shot. While Kane ended his Champions League debut for Bayern with an assist and a goal, the first came courtesy of Onana. As Bayern made an undistinguished start, the best pass Kane received in the first 27 minutes came from Hojlund, United transfer targets in various summers inadvertently combining. But then Sane cut infield, used Kane to play a one-two and shot. Gently. Towards Onana. But the ball squirmed under him, somehow. In a sense, it was a mistake that cost United two goals. They are a side with a capacity to struggle immediately after a setback and, for the third time already this season, they conceded twice in five minutes. The magnificent Musiala was the instigator of the second, a driving run drawing in three United defenders. In the process, they left Gnabry unmarked for him to steer in a shot. Onana neglected to dive this time, perhaps wary of what happened the previous time he did. But it meant there were unwanted similarities with Saturday. As they had against Brighton, United started well. As they did then, they unravelled before the interval. Ten Hag had ditched his midfield diamond and United had a glorious opportunity to open the scoring. After Alphonso Davies made a terrific recovery challenge on Facundo Pellestri, the ball fell obligingly for Christian Eriksen. Perhaps unable to believe how good a chance it was, he shot tamely at Sven Ulreich. Another Dane struck instead for United; it is a goal that may have a long-term significance. It was a first repayment of Hojlund’s £72m fee not, after his cameo at Arsenal, a first indication the young Dane is not intimidated by his price or the pressure it confers. After Bruno Fernandes and Marcus Rashford combined, he span and shot; perhaps a better goalkeeper than Ulreich would have stopped it and United’s three goals suggested the goalkeeper may yet be Bayern’s undoing. But not here. Bayern responded, with a penalty awarded after the incident was reviewed on a monitor. Dayot Upamecano’s header struck the raised arm of Eriksen. Kane composed himself and beat Onana. And then Bayern, so mediocre at the start, were rampant. Sane rolled a shot against the post, Onana again motionless. The goalkeeper belatedly started making saves, launching a damage-limitation exercise when he had been responsible for the initial damage. Bayern, in a show of strength, were able to send on Kingsley Coman, the scorer of a Champions League final winner. Then came a further exchange of goals, Casemiro first finished while grounded before applying a finishing touch to Fernandes’ free kick. Sandwiched by his pair, Bayern added an ultimately decisive fourth: after Thomas Muller struck the post, another substitute, Mathys Tel, finished emphatically. Shorn of 12 players for various reasons – again, some self-inflicted – United had no such enviable options. Their replacements included three goalkeepers, four rookies and a 35-year-old Jonny Evans. United once beat Bayern because they had Teddy Sheringham and Ole Gunnar Solskjaer as substitutes. In a rematch, they had two late goals, both from Casemiro, but fewer reasons to party like it was 1999. Read More Bayern Munich vs Manchester United player ratings: Kane scores and Musiala shines after Onana howler Arsenal are back in the Champions League — and they look like contenders too Harry Kane on target as Bayern Munich pile misery on Manchester United How Harry Kane unshackled Bayern Munich with a classic move from his Tottenham days Andre Onana owns up to mistake against Bayern: ‘One of my worst games’ Bayern Munich vs Manchester United player ratings: Kane scores after Onana howler

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Defence attorneys for Idaho murders suspect Bryan Kohberger have argued that they don’t have all the DNA evidence from prosecutors at a pivotal motions hearing that could delay the highly anticipated trial. Mr Kohberger gave an awkward smile to the court as he returned to the Latah County Courthouse on Friday where six motions from the defence and the prosecution were being argued, including the process of how he was identified as a suspect and his alibi for the night of the murders. The hearing comes just six weeks before Mr Kohberger is set to stand trial for the 13 November 2022 slayings of University of Idaho students Kaylee Goncalves, Madison Mogen, Xana Kernodle, and Ethan Chapin at their home in Moscow. The proceedings began on Friday with Mr Kohberger’s defence team’s motion to compel prosecutors to share additional DNA evidence – specifically the lab results of three unidentified male DNA samples reportedly found at the crime scene. Prosecutors argued that they have provided everything and that they “can’t provide something that doesn’t exist”. “There has to be some level of trust in discovery,” Judge John Judge said. “You are all sworn attorneys.” He ordered the prosecution to reach back out to the lab to ensure there are no other results that the defence does not have. Mr Kohberger, 28, was a graduate student in criminal justice at Washington State University when he was arrested on 30 December at his parents’ home in Pennsylvania. He was then brought back to Idaho where a grand jury indicted him for the murders in May. A DNA sample from trash collected at Mr Kohberger’s family home was used to link him to a knife sheath found at the scene of the murders. Investigators said, “At least 99.9998% of the male population would be expected to be excluded from the possibility of being the suspect’s biological father.” But his defence team, who claim Mr Kohberger was “out driving” at the time of the killings, has argued against the use of forensic genealogy used to identify him and has asked for all the records from the forensic genealogy work. They are also seeking a stay in the trial proceedings arguing that the grand jury should have reached its conclusion “beyond a reasonable doubt” rather than based on probable cause. Prosecutors strongly oppose these motions. Judge John C Judge could grant, deny, or partially approve any parts of these motions. But depending on how he rules, there could be a delay in the 2 October trial date. Read More Bryan Kohberger’s defence seeks to undercut DNA evidence against him in Idaho murders case Bryan Kohberger finally reveals vague alibi for night of Idaho murders Bryan Kohberger asks judge to throw out Idaho murders indictment as prosecutors demand alibi

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